You know, this is a FANTASTIC meme. It doesn't even have to be villians. I mean, it could be a gang of school kids, a band of pirates, a starship crew or any general group of people. It's a good list of stereotypes to think about when you need a bunch of different people.
Hey, that's a wonderful idea! If you want to go ahead and make a sister-meme to this, I'm cool with it, as long as you can give credit to my original meme on the new meme and link to my old one. But I like where you're going with this idea.
The one villain that is being given money to work with the other villains. You know, like those finicky characters that "work alone" unless they get paid to work for someone for a certain amount of time. Or they could be bribed as in blackmailed with either loved ones, information, etc. Whatever you want to make of it.